(3-trans-Chloroallyl)oxyamine （Chloroamine）

Key Identifiers
CAS No.: 87851-77-2

IUPAC Name: (E)-O-(3-Chloro-2-propenyl)hydroxylamine
Molecular Formula: C₃H₆ClNO
Molecular Weight: 107.54 g/mol
Common Synonyms:
– (3-trans-Chloroallyl)oxyamine
– O-(3-Chloroallyl)hydroxylamine
– (E)-O-(3-Chloro-2-propenyl)hydroxylamine

Physical and Chemical Properties
– **Appearance: Colorless to light yellow liquid or oil .
– **Boiling Point: 209 ºC .
– **Flash Point: 80 ºC .
– **Density: 1.155 .
– **Solubility: Slightly soluble in chloroform and ethyl acetate .
– **Storage Conditions**: Should be stored in an inert atmosphere, preferably in a freezer at temperatures below -20°C .

Safety and Handling
– **Hazard Classification**: It is classified as an irritant. The compound is harmful if swallowed, in contact with skin, or if inhaled .
– **Health Hazards**: It is a corrosive and irritating chemical. Contact with skin and eyes may cause irritation and burns. Inhalation should be avoided .
– **Handling Precautions**: Appropriate protective equipment such as gloves, goggles, and protective clothing should be worn. Use only in well-ventilated areas or under a fume hood. It should be kept away from ignition sources and oxidizing materials .

Applications
– **Agrochemical Intermediate**: Its primary application is as a key intermediate in the synthesis of the herbicide **Clethodim** .
– **Pharmaceutical Research**: It is used in organic synthesis as an amination reagent or building block for more complex molecules .